Solvent-Free Synthesis of 1,8-Dioxo-octahydroxanthenes and 14-Aryl-14H-dibenzo[a,j]xanthenes using Saccharin Sulfonic Acid as an Efficient and Green Catalyst

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An efficient solvent-free synthesis of 1,8-dioxo-octahydroxanthenes by using Fe2(SO4)3.7H2O as catalyst

A facile and efficient protocol for the synthesis of 1,8-dioxo-octahydroxanthenes has been developed by one-pot Knoevenagel condensation, Michael addition and cyclodehydration reaction of dimedone (active methylene carbonyl compound) with aromatic aldehydes in the presence of Iron (III) sulfate hydrate as a solid acidic catalyst under solvent-free conditions. Various aromatic aldehydes were uti...

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an efficient solvent-free synthesis of 1,8-dioxo-octahydroxanthenes by using fe2(so4)3.7h2o as catalyst

a facile and efficient protocol for the synthesis of 1,8-dioxo-octahydroxanthenes has been developed by one-pot knoevenagel condensation, michael addition and cyclodehydration reaction of dimedone (active methylene carbonyl compound) with aromatic aldehydes in the presence of iron (iii) sulfate hydrate as a solid acidic catalyst under solvent-free conditions. various aromatic aldehydes were uti...

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Hydroxylamine-O-sulfonic Acid (HOSA): As a Task Specific Catalyst for the Synthesis of 1,8-Dioxo-octahydroxanthenes under Mild, Green and Solvent-free Condition

A highly efficient procedure for the synthesis of 1,8-dioxo-octahydroxanthenes under mild, green and solvent-free condition by using HOSA as a dual role catalyst is described. This is the first report of catalytic activity of HOSA.

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Melamine trisulfonic acid as a highly efficient catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under solvent-free conditions

Melamine trisulfonic acid (MTSA) is utilized as a highly efficient catalyst for the solvent-free condensation reaction of 2-naphthol (2 eq.) with arylaldehydes (1 eq.) under conventional thermal as well as microwave conditions to give the d

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ژورنال

عنوان ژورنال: E-Journal of Chemistry

سال: 2012

ISSN: 0973-4945,2090-9810

DOI: 10.1155/2012/596862